NCERTCHEM 3D
Complete Syllabus Catalog

NCERT Chemistry Chapters List

Browse chapters across Physical, Inorganic, and Organic Chemistry in a structured syllabus list.

CH01
Class 11Unit 1Physical ChemistrySome Basic Concepts of Chemistry
Some Basic Concepts of Chemistry

Master the fundamental principles of chemistry: particulate nature of matter, SI base units, scientific measurements, the 5 laws of chemical combinations, Dalton’s atomic theory, mole concept, empirical formulas, and solution stoichiometry.

Classification of Matter (Elements, Compounds & Mixtures)SI Base Units & Precision vs. AccuracySignificant Figures & Scientific NotationLaws of Chemical Combination & Avogadro’s HypothesisDalton’s Atomic Theory & Modern Atomic Masses (¹²C Standard)Mole Concept & Avogadro Number (6.022 × 10²³)Empirical and Molecular Formula CalculationsStoichiometry & Limiting ReagentSolution Concentrations: Molarity (M), Molality (m), Mass %, Mole Fraction
CH02
Class 11Unit 2Physical ChemistryStructure of Atom
Structure of Atom

Master atomic theory from first principles: discovery of electron, proton, and neutron; Thomson & Rutherford nuclear models; Planck’s quantum hypothesis & photoelectric effect; Bohr’s quantized planetary model & hydrogen spectra; de Broglie matter waves & Heisenberg uncertainty principle; Schrödinger wave equation, quantum numbers (n, l, ml, ms), orbital shapes, nodes, Aufbau principle, Pauli exclusion, Hund’s rule, and electron configurations (Z = 1 to 30).

Discovery of Subatomic Particles (Cathode Rays, e/m Ratio, Millikan Oil Drop)Rutherford Alpha Scattering Experiment & Nuclear Model of the AtomPlanck’s Quantum Theory & Electromagnetic Radiation (E = hν)Photoelectric Effect: Work Function, Threshold Frequency & Einstein EquationBohr’s Model of Hydrogen Atom & Line Emission Spectra (Lyman, Balmer, Paschen)Dual Nature of Matter (de Broglie Relation: λ = h / mv)Heisenberg Uncertainty Principle (Δx · Δp ≥ h / 4π)Quantum Mechanical Model: Schrödinger Equation & Probability Density (|ψ|²)Quantum Numbers (n, l, ml, ms), Orbital Shapes (s, p, d) & Nodal PlanesAufbau (n+l) Rule, Pauli Exclusion, Hund’s Multiplicity & Cr/Cu Anomalies
CH03
Class 11Unit 3Inorganic ChemistryClassification of Elements and Periodicity in Properties
Classification of Elements and Periodicity in Properties

Master periodic classification from first principles: historical genesis (Dobereiner’s triads, Newlands’ octaves, Lothar Meyer, Mendeleev’s table & predictions for Ga/Ge), Moseley’s Modern Periodic Law & X-ray spectra discovery, long form 7-period/18-group architecture, IUPAC nomenclature for Z > 100, s/p/d/f block characteristics, metals/metalloids/non-metals, periodic trends in atomic & ionic radii, isoelectronic species contraction, ionization enthalpy (ΔiH) & anomalies (Be/B, N/O), electron gain enthalpy (ΔegH) & F/Cl inversion, Pauling electronegativity, oxidation states, second-period anomalous behaviors, diagonal relationships, and acid-base oxide periodicity across Period 3.

Historical Genesis (Dobereiner Triads, Newlands Octaves, Lothar Meyer, Mendeleev Table & Predictions)Modern Periodic Law & Moseley’s X-Ray Discovery: sqrt(ν) = a(Z - b)Long Form Periodic Table Architecture (7 Periods, 18 IUPAC Groups)IUPAC Systematic Nomenclature for Superheavy Elements (Z > 100)Division into s, p, d, and f Blocks & Electronic Configuration CorrelationMetals, Non-Metals, and Metalloids along the Diagonal BoundaryAtomic Radii (Covalent, Metallic, Van der Waals) & Effective Nuclear Charge (Zeff)Ionic Radii & Isoelectronic Series Contraction (N³⁻ > O²⁻ > F⁻ > Na⁺ > Mg²⁺ > Al³⁺)Ionization Enthalpy: Successive IE, Factors & Anomalies (Be vs B, N vs O, Ga vs Al)Electron Gain Enthalpy: Exothermic vs Endothermic & Cl vs F InversionElectronegativity (Pauling Scale) & Metallic vs Non-Metallic GradationValence & Oxidation States in Hydrides and Highest OxidesAnomalous Properties of Second Period Elements (Li to F) & Covalency Capped at 4Diagonal Relationships (Li-Mg, Be-Al, B-Si) & Charge-to-Radius RatioPeriodic Acid-Base Trends in Period 3 Oxides (Na2O to Cl2O7) with Water Reactions
CH04
Class 11Unit 4Inorganic ChemistryChemical Bonding and Molecular Structure
Chemical Bonding and Molecular Structure

Master chemical bonding from first principles: Kössel-Lewis octet framework and Lewis dot structures, ionic bond energetics and Born-Haber lattice enthalpy (NaCl: -788 kJ/mol), bond parameters (radii, angles, average bond enthalpies, resonance hybrids), bond polarity and dipole moments (Debye units, NH3 vs NF3 vector opposition, Fajans rules), VSEPR 3D geometries and lone-pair repulsion hierarchy (CH4, NH3, H2O, PCl5 axial bond elongation, SF4, ClF3, XeF4), Valence Bond Theory potential energy curves and sigma/pi overlaps, Pauling hybridisation (sp, sp2, sp3, sp3d, sp3d2), Molecular Orbital Theory with 2s-2p mixing (Z <= 7 vs Z > 7), bond order calculation, paramagnetism of O2, double bond in C2, and hydrogen bonding (inter vs intra, ice cage density anomaly at 4°C).

Kössel-Lewis Approach, Octet Rule & Group Valency from Lewis SymbolsSystematic Lewis Dot Structures & Formal Charge Calculation (FC = V - L - 1/2 S)Octet Limitations (Incomplete Octet, Odd-Electron NO/NO2, Expanded Octet PF5/SF6, Noble Gas XeF2/XeF4)Ionic Bond Energetics: Ionization Enthalpy, Electron Gain Enthalpy & Born-Haber Lattice EnthalpyBond Parameters: Covalent vs Van der Waals Radii, Bond Lengths & Polyatomic Mean Bond EnthalpiesResonance Phenomenon: Canonical Forms, True Resonance Hybrids & Stabilization Energy (O3, CO3²⁻, CO2)Dipole Moments (μ = q × d, Debye Units) & Vector Resolution: NH3 (1.47 D) vs NF3 (0.23 D)Fajans Rules for Partial Covalent Character in Ionic Bonds (Cation Polarizing Power & Anion Polarisability)VSEPR Theory & Repulsion Hierarchy: LP-LP > LP-BP > BP-BP with Ideal vs Distorted Bond AnglesTrigonal Bipyramidal Asymmetry: Why PCl5 Axial Bonds (240 pm) are Longer & More Reactive than Equatorial (202 pm)Valence Bond Theory: H2 Potential Energy Curve (74 pm, 435.8 kJ/mol) & Positive/Negative/Zero OverlapsSigma (σ) Axial vs Pi (π) Lateral Bonds & Relative Overlap Strengths in Multiple BondsPauling Hybridisation: sp, sp², sp³, sp³d, sp³d² Orbital Mechanisms in Hydrocarbons & InorganicsMolecular Orbital Theory (MOT): LCAO Principles, Bonding (σ, π) vs Antibonding (σ*, π*) & Nodal Planes2s-2p Orbital Mixing (Z ≤ 7: B2, C2, N2) vs No Mixing (Z > 7: O2, F2) & Aufbau/Hund Spin PopulationMOT Bond Order Formula (BO = 1/2 [Nb - Na]), Paramagnetism of O2 & Pure Pi Double Bond in C2Hydrogen Bonding (F, O, N): Intermolecular (p-nitrophenol) vs Intramolecular Chelation (o-nitrophenol)Ecological Consequences of H-Bonding: Ice Open Cage Structure, Water Density Maximum at 4°C & Hydride BPs
CH05
Class 11Unit 5Physical ChemistryChemical Thermodynamics
Chemical Thermodynamics

Master chemical thermodynamics from first principles: open, closed, and isolated systems; state functions vs path functions; First Law of Thermodynamics and internal energy; reversible vs irreversible pressure-volume work; enthalpy, calorimetry (bomb vs constant pressure), and heat capacities (Cp - Cv = R); standard formation enthalpies, Hess’s law of heat summation, bond enthalpies, and lattice energy via Born-Haber cycle; spontaneity, entropy, Second Law, and Gibbs free energy (ΔG = ΔH - TΔS); Third Law absolute zero entropy, and the thermodynamic equilibrium constant (ΔrG° = -RT ln K).

Thermodynamic Systems (Open, Closed, Isolated) & Real vs Imaginary BoundariesState Functions & Variables (p, V, T, n) vs Path Functions (q, w)Extensive vs Intensive Properties & Container Partition PrincipleInternal Energy (U), Adiabatic Work (Joule Equivalent) & First Law (ΔU = q + w)IUPAC Sign Conventions for Heat (q) and Work (w)Pressure-Volume Work: Irreversible (w = -Pex ΔV) vs Reversible Isothermal (w = -2.303 nRT log(Vf/Vi))Enthalpy (H = U + pV), Heat at Constant Pressure (qp = ΔH), and Gas Expansion (ΔH = ΔU + Δng RT)Heat Capacity (C), Specific Heat (c), Molar Heat Capacity (Cm), and Meyer Relation (Cp - Cv = R)Calorimetry: Constant-Volume Bomb Calorimeter (ΔU = qV) vs Constant-Pressure Coffee Cup (ΔH = qp)Standard States (1 bar, 298 K) & Standard Enthalpy of Formation (ΔfH° = 0 for reference elements)Hess’s Law of Constant Heat Summation & Multi-Step Reaction CyclesEnthalpies of Phase Changes (Fusion, Vaporization, Sublimation) & Combustion (ΔcH°)Bond Dissociation Enthalpies & Mean Bond Enthalpy in Polyatomics: ΔrH° ≈ Σ BE(broken) - Σ BE(formed)Lattice Enthalpy (ΔlatticeH°) & Born-Haber Cycle for Ionic Crystals (NaCl)Enthalpy of Solution (ΔsolH° = ΔlatticeH° + ΔhydH°) & Enthalpy of DilutionSpontaneity Criteria: Failure of Enthalpy Decrease Alone & Spontaneous Endothermic ReactionsEntropy (S) as Randomness/Disorder & Thermodynamic Definition (ΔS = qrev / T)Second Law of Thermodynamics: ΔStotal = ΔSsys + ΔSsurr > 0 for Spontaneous ProcessesGibbs Free Energy (G = H - TS), Spontaneity Criterion (ΔG < 0), and Four Quadrants (Table 5.4)Third Law of Thermodynamics: Absolute Zero Crystal Entropy (lim T->0 K S = 0)Gibbs Energy and Chemical Equilibrium Constant (ΔrG° = -RT ln K = -2.303 RT log K)
CH06
Class 11Unit 6Physical ChemistryEquilibrium
Equilibrium

Master dynamic chemical and ionic equilibria from first principles: dynamic phase and chemical equilibria (Haber deuterium scrambling); Law of Mass Action and equilibrium constants (Kc, Kp = Kc(RT)^Δn); reaction quotient (Qc) and thermodynamic connection (ΔrG° = -RT ln K); Le Chatelier’s principle (concentration, pressure, volume, temperature via van ’t Hoff, inert gas, and catalyst invariance); Arrhenius, Brönsted-Lowry, and Lewis acid-base theories; autoionization of water and ionic product (Kw = 1.0 × 10⁻¹⁴); logarithmic pH scale; weak acid/base ionization (Ka, Kb) and Ostwald’s dilution law; polyprotic acids and common-ion effect; salt hydrolysis in all 4 categories; buffer solutions and Henderson-Hasselbalch equations; and sparingly soluble salts, solubility product (Ksp), precipitation criteria (Qsp > Ksp), common-ion suppression, and pH-dependent solubility.

Dynamic Equilibrium in Physical Phase Processes (Solid-Liquid, Liquid-Vapour, Solid-Vapour)Dynamic Nature of Chemical Equilibrium & Haber Deuterium (D2) Isotope ScramblingLaw of Mass Action & Equilibrium Constant Expression (Kc = [C]^c [D]^d / [A]^a [B]^b)Gaseous Homogeneous Equilibria & Relation Between Kp and Kc (Kp = Kc (RT)^Δn)Heterogeneous Equilibria & Invariant Constant Activity of Pure Solids and Pure LiquidsReaction Quotient (Qc) & Direction of Reaction (Qc < Kc forward, Qc > Kc reverse, Qc = Kc equilibrium)Thermodynamic Equilibrium Link: ΔrG° = -RT ln K = -2.303 RT log KLe Chatelier’s Principle: Perturbations in Concentration (Fe³⁺-SCN⁻ Blood-Red Complex)Effect of Pressure, Volume, and Inert Gas Addition (Constant Volume vs Constant Pressure)Effect of Temperature & van ’t Hoff Equation: Exothermic (K decreases) vs Endothermic (K increases)Catalyst Invariance: Activation Energy Lowering Without Changing Equilibrium Position or KcMichael Faraday Electrolyte Classification: Strong vs Weak Electrolytes & Dielectric ShieldingAcid-Base Theoretical Frameworks: Arrhenius, Brönsted-Lowry, and Lewis ConceptsAutoionization of Water, Ionic Product (Kw = [H⁺][OH⁻] = 10⁻¹⁴ at 298 K) & Temperature DependenceLogarithmic pH Scale (pH = -log[H⁺], pH + pOH = 14) & 4-Strip pH Paper DiagnosticsWeak Acid and Weak Base Ionization Constants (Ka, Kb) & Ostwald’s Dilution Law (α ≈ √(K/c))Conjugate Acid-Base Pairs Relation: Ka × Kb = Kw & pKa + pKb = 14.00Polybasic Acids (Ka1 >> Ka2 >> Ka3) & Electrostatic Proton Detachment BarrierCommon-Ion Effect: Suppression of Weak Electrolyte Dissociation by Added Common IonsHydrolysis of Salts: 4 Distinct Categories & Analytical pH FormulationsBuffer Solutions: Acidic & Basic Buffers, Henderson-Hasselbalch Equation & Dilution InvarianceSolubility Equilibria of Sparingly Soluble Salts & Solubility Product Constant (Ksp)Precipitation Prediction Criteria: Ionic Product Qsp vs Ksp (Qsp > Ksp Precipitates)Common-Ion Effect on Solubility (NaCl / HCl Gas & Qualitative Cation Analysis)pH-Dependent Solubility of Salts of Weak Acids: S = √(Ksp([H⁺] + Ka) / Ka)